New technique paves the way for production of perovskite solar cells

The technique is low-cost, simple, energy-efficient, and should pave the way for large scale deployment of perovskite solar cells. Perovskite is of interest for solar cells because it absorbs light very efficiently. This allows for the creation of lightweight, flexible solar cells that can be incorporated into a range of technologies, such as the windows of buildings or vehicles.

“What we’ve done here is demonstrate that you can produce perovskite photovoltaics on larger substrates using spin coating by designing a co-solvent dilution strategy,” says Michael Grätzel, who is the lead co-corresponding author of a paper on the work and a professor at École Polytechnique Fédérale de Lausanne. “The new technique also significantly reduces waste and, by extension, reduces toxic byproducts associated with manufacturing perovskite photovoltaics.”

“Typically, there is a direct correlation between the thickness of the semiconductor film and the precursor ink concentration. Therefore, the high-efficiency perovskite solar cells require a high concentration (>1.4 M) of lead components to obtain thick and high-quality films. Encouragingly, our co-solvent dilution strategy breaks this general rule.” Hong Zhang says, first-author on the paper.

“In the lab, researchers produce perovskite photovoltaic materials using a technique called spin coating, which creates a thin film of perovskite on a substrate – but only on a small scale,” says Aram Amassian, who is a professor at the North Carolina State University. “We’re talking about sample substrates that are only one or two square centimeters in size. However, people didn’t think it was possible to scale spin-coating up for manufacturing, using substrates that are tens of centimeters square. Instead, people have opted for a variety of other methods. But these other methods produce perovskite photovoltaics that don’t perform as well as the thin films made using spin coating and required significant research and development.”

Historically, people thought spin coating could not be used to produce perovskite photovoltaics on industrial-scale substrates in a material-efficient way because of the nature of both spin coating and perovskites.

Spin coating involves placing a liquid on the surface of a substrate and then spinning the substrate, so that the liquid material spreads across the surface. However, when perovskite is applied using this technique, the solvents that keep the perovskite in a liquid state don’t evaporate quickly enough. This causes much of the perovskite to fly off the edges, meaning a lot of the perovskite material is wasted. It also results in irregular thickness of the perovskite on the surface, as well as some areas of the perovskite taking longer than others to dry. All of which is problematic from a manufacturing standpoint.

“The beauty of this technique is that many industries already use spin coating technologies to produce all sorts of products,” Aldo Di Carlo says, who is professor at the University of Rome Tor Vergata. “Our work demonstrates that these existing technologies could be used to create perovskite solar cells. This could really accelerate the production and deployment of perovskite solar panels and cells.”

Collaborators on the demonstration project are already using the new technique to produce modules that are tens of centimeters across with excellent uniformity and performance.

The paper, “A universal co-solvent dilution strategy enables facile and cost-effective fabrication of perovskite photovoltaics,” is published in the journal Nature Communications 13, 89 (2022), DOI: https://www.nature.com/articles/s41467-021-27740-4. Lead authors of the paper are Hong Zhang of École Polytechnique Fédérale de Lausanne; Kasra Darabi, a Ph.D. student at NC State; and Narges Yaghoobi Nia of University of Rome Tor Vergata. Co-corresponding authors are Michael Grätzel of École Polytechnique Fédérale de Lausanne, Aram Amassian of North Carolina State University, Aldo Di Carlo of University of Rome Tor Vergata.

The work was done with support from the European Union’s Horizon 2020 research and innovation program (GRAPHENE Flagship Core 3 grant agreement No. 881603 as well as Espresso under agreement No. 764047), the Swiss National Science Foundation, the Italian Ministry of Economic Development, and the U.S. Office of Naval Research.