Hydrogen fuel from sunlight.

© 2011 EPFL

© 2011 EPFL

Highly active oxide photocathode for photoelectrochemical water reduction.

A clean and efficient way to overcome the limited supply of fossil fuels and the greenhouse effect is the production of hydrogen fuel from sunlight and water through the semiconductor/water junction of a photoelectrochemical cell, where energy collection and water electrolysis are combined into a single semiconductor electrode. The group of Prof. Michaël Grätzel (LPI - Laboratory of Photonics and Interfaces) present a highly active photocathode for solar H2 production, consisting of electrodeposited cuprous oxide, which was protected against photocathodic decomposition in water by nanolayers of Al-doped zinc oxide and titanium oxide and activated for hydrogen evolution with electrodeposited Pt nanoparticles.

Adriana Paracchino et al., Nature Materials, doi:10.1038/nmat3017 (2011)