Congratulations to Petru for his Nature Materials paper!

© 2024 EPFL

© 2024 EPFL

Can we design catalysts which are stable, yet preserve their activity? Can we imagine new materials where inorganic and organic buidling blocks come together to synergistically provide the properties that we seek for?

One of the biggest challenges for a more sustainable society is to have active and stable catalysts which enable the transition from fossil to renewable feedstocks, reduce energy consumption, and minimize the environmental footprint. Herein, we synthesize novel hybrid materials where an amorphous oxide coating with embedded organic ligands surrounds metallic nanocrystals. We demonstrate that the hybrid coating is a powerful mean to create electrocatalysts stable against structural reconstruction during the CO2 electroreduction. These electrocatalysts consists of copper nanocrystals encapsulated in a hybrid organic/inorganic alumina shell grown by our colloidal atomic layer deposition method. The synthetic tunability of the chemistry developed herein opens new avenues for the design of stable electrocatalysts and beyond. Read more here!